Na Li defeated Svetlana Kuznetsova 3-6 6-2 6-3 in the Wimbledon round of 32 on grass. The upset overturned the form book — Svetlana Kuznetsova came in leading the head-to-head 6–3, defending last year's quarter-final. Na Li narrowed the head-to-head to 6–4.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2011-01-10 | Sydney | QF | hard | Na Li | 3-6 7-6(4) 6-3 |
| 2010-04-26 | Stuttgart | R16 | clay | Na Li | 6-3 7-5 |
| 2009-04-27 | Stuttgart | R16 | clay | Svetlana Kuznetsova | 4-6 6-4 7-5 |
| 2008-10-06 | Moscow | R32 | hard | Svetlana Kuznetsova | 6-4 7-5 |
| 2008-09-15 | Tokyo | R32 | hard | Svetlana Kuznetsova | 6-2 1-6 6-3 |
| 2008-08-11 | Olympics | R64 | hard | Na Li | 7-6(5) 6-4 |
| 2006-09-18 | Beijing | QF | hard | Svetlana Kuznetsova | 6-4 4-6 6-4 |
| 2006-05-29 | Roland Garros | R32 | clay | Svetlana Kuznetsova | 6-3 7-6(4) |
| 2004-09-20 | Beijing | R16 | hard | Svetlana Kuznetsova | 6-3 6-7(6) 7-6(3) |
Each player's serve crossed against the other's return, converted to expected hold of serve. Recent completed matches, ATP, WTA & Challenger. About
Averages over each player's completed matches in the selected window (200 vs 197). ATP, WTA & Challenger.
Performance in the biggest moments — break points, deciding sets and tiebreaks (0–100, higher is better). About