Alicia Molik defeated Venus Williams 7-5 7-6 in the Australian Open round of 16 on hard. The upset overturned the form book — Venus Williams came in leading the head-to-head 4–0, defending last year's round of 32, but Alicia Molik had been the form player, winning 2 of their last 6 on hard. Alicia Molik claimed a first win over Venus Williams in five meetings, narrowing the head-to-head to 4–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2007-10-01 | Japan Open | QF | hard | Venus Williams | 7-6(4) 6-3 |
| 2004-02-23 | Dubai | R16 | hard | Venus Williams | 6-3 6-4 |
| 2002-08-26 | US Open | R64 | hard | Venus Williams | 6-1 6-2 |
| 1999-05-24 | Roland Garros | R32 | clay | Venus Williams | 6-3 6-1 |
Each player's serve crossed against the other's return, converted to expected hold of serve. Recent completed matches, ATP, WTA & Challenger. About
Averages over each player's completed matches in the selected window (74 vs 199). ATP, WTA & Challenger.
Performance in the biggest moments — break points, deciding sets and tiebreaks (0–100, higher is better). About