Venus Williams defeated Alicia Molik 6-1 6-2 in the US Open round of 64 on hard. The result followed the form book — Venus Williams came in leading the head-to-head 3–1, defending the title. Venus Williams extended the head-to-head to 4–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2007-10-01 | Japan Open | QF | hard | Venus Williams | 7-6(4) 6-3 |
| 2005-01-17 | Australian Open | R16 | hard | Alicia Molik | 7-5 7-6(3) |
| 2004-02-23 | Dubai | R16 | hard | Venus Williams | 6-3 6-4 |
| 1999-05-24 | Roland Garros | R32 | clay | Venus Williams | 6-3 6-1 |
Each player's serve crossed against the other's return, converted to expected hold of serve. Recent completed matches, ATP, WTA & Challenger. About
Averages over each player's completed matches in the selected window (199 vs 89). ATP, WTA & Challenger.
Performance in the biggest moments — break points, deciding sets and tiebreaks (0–100, higher is better). About