Alvaro Peiro Serrano defeated Darius Florin Pop 6-3 6-0 in the M25 Valencia 1 round of 32 on clay. Alvaro Peiro Serrano narrowed the head-to-head to 3–2.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2025-08-18 | M25 Santander 1 | Q16 | clay | Alvaro Peiro Serrano | 4-6 6-4 12-10 |
| 2025-02-12 | M15 Valencia 2 | R32 | clay | Darius Florin Pop | 6-4 7-6(1) |
| 2023-12-03 | M15 Madrid 3 | Q64 | clay | Darius Florin Pop | 6-0 6-1 |
| 2023-11-12 | M15 Valencia 1 | Q64 | clay | Darius Florin Pop | 6-0 6-4 |
Averages over each player's completed matches in the selected window. ATP, WTA & Challenger.