Carolina Pillot defeated Agnese Zucchini 6-3 7-5 in the Imola 25K round of 32 on carpet. The upset overturned the form book — Agnese Zucchini came in leading the head-to-head 1–0. Carolina Pillot claimed a first win over Agnese Zucchini in two meetings, narrowing the head-to-head to 1–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2012-09-24 | Madrid 10K | QF | clay | Agnese Zucchini | 6-1 6-1 |