Agnese Zucchini defeated Carolina Pillot 6-1 6-1 in the Madrid 10K qualifying round on clay. The upset overturned the form book — Carolina Pillot came in leading the head-to-head 1–0. Agnese Zucchini claimed a first win over Carolina Pillot in two meetings, narrowing the head-to-head to 1–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2013-07-15 | Imola 25K | R32 | carpet | Carolina Pillot | 6-3 7-5 |