Antoine Benneteau defeated Charles Antoine Brezac 6-4 1-6 7-5 in the France F16 round of 32 on hard. The upset overturned the form book — Charles Antoine Brezac came in leading the head-to-head 1–0. Antoine Benneteau claimed a first win over Charles Antoine Brezac in two meetings, narrowing the head-to-head to 1–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2012-09-17 | France F17 | R16 | hard | Charles Antoine Brezac | 7-6(5) 6-7(4) 6-4 |