Federica Quercia defeated Silvia Garcia Jimenez 6-3 6-3 in the Monteroni D'Arbia 25K q16 on clay. The upset overturned the form book — Silvia Garcia Jimenez came in leading the head-to-head 1–0. Federica Quercia claimed a first win over Silvia Garcia Jimenez in two meetings, narrowing the head-to-head to 1–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2012-04-02 | Torrent 10K | R32 | clay | Silvia Garcia Jimenez | 6-4 6-1 |