Na Li defeated Maria Sharapova 6-4 7-5 in the Roland Garros semi-final on clay. The upset overturned the form book — Maria Sharapova came in leading the head-to-head 10–4, defending last year's round of 32. Na Li narrowed the head-to-head to 10–5.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2014-05-05 | Madrid | QF | clay | Maria Sharapova | 2-6 7-6(5) 6-3 |
| 2013-04-22 | Stuttgart | F | clay | Maria Sharapova | 6-4 6-3 |
| 2013-01-14 | Australian Open | SF | hard | Na Li | 6-2 6-2 |
| 2012-10-01 | Beijing | SF | hard | Maria Sharapova | 6-4 6-0 |
| 2012-05-14 | Rome | F | clay | Maria Sharapova | 4-6 6-4 7-6(5) |
| 2012-03-19 | Miami | QF | hard | Maria Sharapova | 6-3 6-0 |
| 2011-10-24 | WTA Championships | RR | hard | Na Li | 7-6(4) 6-4 |
| 2010-06-07 | Birmingham | F | grass | Na Li | 7-5 6-1 |
| 2009-06-08 | Birmingham | SF | grass | Na Li | 6-4 6-4 |
| 2009-05-25 | Roland Garros | R16 | clay | Maria Sharapova | 6-4 0-6 6-4 |
| 2006-08-28 | US Open | R16 | hard | Maria Sharapova | 6-4 6-2 |
| 2006-06-12 | Birmingham | R16 | grass | Maria Sharapova | 6-2 6-4 |
| 2006-03-20 | Miami | R64 | hard | Maria Sharapova | 6-2 6-4 |
| 2005-01-17 | Australian Open | R32 | hard | Maria Sharapova | 6-0 6-2 |
Each player's serve crossed against the other's return, converted to expected hold of serve. Recent completed matches, ATP, WTA & Challenger. About
Averages over each player's completed matches in the selected window (175 vs 198). ATP, WTA & Challenger.
Performance in the biggest moments — break points, deciding sets and tiebreaks (0–100, higher is better). About