Natalie Piquion defeated Emilie Bacquet 6-3 6-3 in the Amiens 10K round of 32 on clay. The upset overturned the form book — Emilie Bacquet came in leading the head-to-head 4–0. Natalie Piquion claimed a first win over Emilie Bacquet in five meetings, narrowing the head-to-head to 4–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2006-08-14 | Koksijde 10K | R32 | clay | Emilie Bacquet | 6-2 6-4 |
| 2006-08-07 | Rebecq 10K | R16 | clay | Emilie Bacquet | 6-0 7-5 |
| 2005-11-14 | Deauville 50K | R32 | clay | Emilie Bacquet | 6-3 6-2 |
| 2005-11-07 | Le Havre 10K | SF | clay | Emilie Bacquet | 6-1 6-2 |