Rossana De Los Rios defeated Marta Marrero 6-4 6-3 in the Saint Malo 100K round of 32 on clay. Rossana De Los Rios extended the head-to-head to 2–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2003-04-07 | Estoril | R32 | clay | Rossana De Los Rios | 3-6 6-3 3-3 |
| 2000-05-29 | Roland Garros | R16 | clay | Marta Marrero | 4-6 6-0 6-4 |
Averages over each player's completed matches in the selected window. ATP, WTA & Challenger.