Venus Williams defeated Anna Chakvetadze 6-0 6-7 6-4 in the Rome round of 16 on clay. The result followed the form book — Venus Williams came in leading the head-to-head 2–1, defending last year's quarter-final. Venus Williams extended the head-to-head to 3–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2007-07-30 | San Diego | QF | hard | Anna Chakvetadze | 6-7(5) 7-6(3) 6-2 |
| 2007-07-14 | Fed Cup WG SF: USA vs RUS | RR | hard | Venus Williams | 6-1 6-4 |
| 2005-05-16 | Istanbul | QF | clay | Venus Williams | 6-2 6-1 |
Each player's serve crossed against the other's return, converted to expected hold of serve. Recent completed matches, ATP, WTA & Challenger. About
Averages over each player's completed matches in the selected window (199 vs 83). ATP, WTA & Challenger.
Performance in the biggest moments — break points, deciding sets and tiebreaks (0–100, higher is better). About