Na Li defeated Victoria Azarenka 4-6 6-3 6-4 in the Gold Coast final on hard. The upset overturned the form book — Victoria Azarenka came in leading the head-to-head 6–4. Na Li narrowed the head-to-head to 6–5.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2013-10-21 | WTA Championships | RR | hard | Na Li | 6-2 6-1 |
| 2013-01-14 | Australian Open | F | hard | Victoria Azarenka | 4-6 6-4 6-3 |
| 2012-10-22 | WTA Championships | RR | hard | Victoria Azarenka | 7-6(4) 6-3 |
| 2012-05-07 | Madrid | QF | clay | Victoria Azarenka | 3-6 6-3 6-3 |
| 2012-01-09 | Sydney | F | hard | Victoria Azarenka | 6-2 1-6 6-3 |
| 2011-10-24 | WTA Championships | RR | hard | Victoria Azarenka | 6-2 6-2 |
| 2011-05-23 | Roland Garros | QF | clay | Na Li | 7-5 6-2 |
| 2011-01-17 | Australian Open | R16 | hard | Na Li | 6-3 6-3 |
| 2010-08-16 | Montreal | R16 | hard | Victoria Azarenka | 6-3 6-3 |
| 2009-09-28 | Tokyo | QF | hard | Na Li | 7-6(7) 4-6 7-6(4) |
Each player's serve crossed against the other's return, converted to expected hold of serve. Recent completed matches, ATP, WTA & Challenger. About
Averages over each player's completed matches in the selected window (200 vs 195). ATP, WTA & Challenger.
Performance in the biggest moments — break points, deciding sets and tiebreaks (0–100, higher is better). About