Maria Penkova defeated Alexandra Popa 6-2 6-3 in the Bucharest 4 10K qualifying round on clay. The result followed the form book — Maria Penkova came in leading the head-to-head 1–0. Maria Penkova extended the head-to-head to 2–0.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2006-09-04 | Bucharest 6 10K | R32 | clay | Maria Penkova | 4-6 6-2 6-2 |