Alice Balducci defeated Maria Belen Corbalan 7-6 6-4 in the Imola Tozzona 10K round of 16 on carpet. The upset overturned the form book — Maria Belen Corbalan came in leading the head-to-head 3–0. Alice Balducci claimed a first win over Maria Belen Corbalan in four meetings, narrowing the head-to-head to 3–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2006-08-21 | Tre Castagni 10K | R16 | hard | Maria Belen Corbalan | 3-6 6-3 6-4 |
| 2005-09-12 | Torre Del Greco 10K | R32 | clay | Maria Belen Corbalan | 6-4 6-3 |
| 2005-08-29 | Vittoria 10K | QF | clay | Maria Belen Corbalan | 6-1 6-2 |