Josanne Van Bennekom defeated Nadejda Vassileva 6-4 7-5 in the Galati 10K qualifying round on clay. The upset overturned the form book — Nadejda Vassileva came in leading the head-to-head 1–0. Josanne Van Bennekom claimed a first win over Nadejda Vassileva in two meetings, narrowing the head-to-head to 1–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2006-06-19 | Bucharest 3 10K | R16 | clay | Nadejda Vassileva | 6-0 6-1 |