Na Li defeated Anna Chakvetadze 7-5 6-3 in the Roland Garros round of 64 on clay. The upset overturned the form book — Anna Chakvetadze came in leading the head-to-head 3–1, defending last year's round of 32. Na Li narrowed the head-to-head to 3–2.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2010-10-18 | Moscow | R32 | hard | Anna Chakvetadze | 6-4 6-2 |
| 2008-02-18 | Doha | R32 | hard | Na Li | 7-6(7) 6-4 |
| 2007-03-19 | Miami | QF | hard | Anna Chakvetadze | 4-6 7-5 6-2 |
| 2005-08-08 | Los Angeles | R64 | hard | Anna Chakvetadze | 7-5 6-4 |
Each player's serve crossed against the other's return, converted to expected hold of serve. Recent completed matches, ATP, WTA & Challenger. About
Averages over each player's completed matches in the selected window (200 vs 199). ATP, WTA & Challenger.
Performance in the biggest moments — break points, deciding sets and tiebreaks (0–100, higher is better). About