Nadja Pavic defeated Valentina Sassi 5-7 6-1 6-0 in the Patras 25K round of 32 on hard. The upset overturned the form book — Valentina Sassi came in leading the head-to-head 1–0. Nadja Pavic claimed a first win over Valentina Sassi in two meetings, narrowing the head-to-head to 1–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2006-07-24 | Monteroni D`Arbia 25K | R32 | clay | Valentina Sassi | 7-6(5) 2-6 6-1 |