Florencia Molinero defeated Carla Tiene 6-4 4-6 6-0 in the Montemor-o-Novo 10K qualifying round on hard. Florencia Molinero extended the head-to-head to 2–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2006-04-10 | San Luis Potosi 25K | R16 | clay | Carla Tiene | 6-1 6-3 |
| 2005-06-06 | Nazare 10K | SF | hard | Florencia Molinero | 6-1 6-4 |
Averages over each player's completed matches in the selected window. ATP, WTA & Challenger.