Alicia Molik defeated Jelena Jankovic 6-3 6-4 in the Sydney round of 16 on hard. The upset overturned the form book — Jelena Jankovic came in defending last year's round of 32, but Alicia Molik had been the form player, winning 2 of their last 4 on hard. Alicia Molik extended the head-to-head to 4–3.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2010-05-24 | Roland Garros | R128 | clay | Jelena Jankovic | 6-0 6-4 |
| 2006-09-25 | Guangzhou | QF | hard | Jelena Jankovic | 6-3 7-5 |
| 2005-10-17 | Zurich | R32 | hard | Jelena Jankovic | 6-3 4-2 RET |
| 2004-11-01 | Philadelphia | R16 | carpet | Alicia Molik | 7-5 6-3 |
| 2004-06-07 | Birmingham | R16 | grass | Alicia Molik | 6-3 6-2 |
| 2004-04-05 | Amelia Island | R64 | clay | Alicia Molik | 6-0 6-0 |
Each player's serve crossed against the other's return, converted to expected hold of serve. Recent completed matches, ATP, WTA & Challenger. About
Averages over each player's completed matches in the selected window (75 vs 200). ATP, WTA & Challenger.
Performance in the biggest moments — break points, deciding sets and tiebreaks (0–100, higher is better). About