Venus Williams defeated Vera Zvonareva 6-3 6-4 in the Charleston quarter-final on clay. Venus Williams extended the head-to-head to 7–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2010-05-10 | Madrid | R32 | clay | Venus Williams | 7-5 6-3 |
| 2008-11-03 | WTA Tour Championships | F | carpet | Venus Williams | 6-7(5) 6-0 6-2 |
| 2008-05-12 | Rome | R16 | clay | Venus Williams | 7-5 6-2 |
| 2008-03-03 | Bangalore | QF | hard | Venus Williams | 6-4 6-3 |
| 2004-04-26 | Warsaw | SF | clay | Venus Williams | 6-3 6-2 |
| 2003-06-23 | Wimbledon | R16 | grass | Venus Williams | 6-1 6-3 |
| 2003-05-26 | Roland Garros | R16 | clay | Vera Zvonareva | 2-6 6-2 6-4 |
Each player's serve crossed against the other's return, converted to expected hold of serve. Recent completed matches, ATP, WTA & Challenger. About
Averages over each player's completed matches in the selected window (199 vs 199). ATP, WTA & Challenger.
Performance in the biggest moments — break points, deciding sets and tiebreaks (0–100, higher is better). About