Carlos Rexach Itoiz defeated Angel Jose Martin 6-2 6-1 in the Spain F1 round of 32 on clay. The upset overturned the form book — Angel Jose Martin came in leading the head-to-head 1–0. Carlos Rexach Itoiz claimed a first win over Angel Jose Martin in two meetings, narrowing the head-to-head to 1–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2000-08-28 | Spain F8 | QF | clay | Angel Jose Martin | 5-3 4-1 5-4(3) |