Angeles Montolio defeated Rossana De Los Rios 7-5 6-4 in the Madrid quarter-final on clay. The result followed the form book — Angeles Montolio came in leading the head-to-head 1–0, defending last year's quarter-final. Angeles Montolio extended the head-to-head to 2–0.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2001-05-14 | Rome | R64 | clay | Angeles Montolio | 6-4 7-5 |
Averages over each player's completed matches in the selected window. ATP, WTA & Challenger.