Venus Williams advanced past Anke Huber via walkover in the Zurich round of 16. Venus Williams extended the head-to-head to 4–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 2000-05-29 | Roland Garros | R16 | clay | Venus Williams | 7-6(4) 6-2 |
| 1999-03-18 | Key Biscayne | R16 | hard | Venus Williams | 6-3 5-7 7-6 |
| 1997-08-25 | US Open | R32 | hard | Venus Williams | 6-3 6-4 |
| 1997-08-04 | Manhattan Beach | R16 | hard | Anke Huber | 7-6 6-4 |
Averages over each player's completed matches in the selected window. ATP, WTA & Challenger.