Ann Grossman defeated Natalia Zvereva 4-6 6-1 6-4 in the Roland Garros round of 64 on clay. The upset overturned the form book — Natalia Zvereva came in leading the head-to-head 1–0, defending last year's round of 32. Ann Grossman claimed a first win over Natalia Zvereva in two meetings, narrowing the head-to-head to 1–1.
| Date | Tournament | Round | Surface | Winner | Score |
|---|---|---|---|---|---|
| 1995-08-28 | US Open | R32 | hard | Natalia Zvereva | 6-4 7-6 |